Nanoflower-Like High-Entropy Co-Fe-Cr-Mo-Mn Spinel for Oxygen Evolution

Oxygen evolution reaction (OER) is the key anode reaction of electrolytic water. To improve the slow OER kinetics, we synthesize nanoflower-like Co-Fe-Cr-Mo-Mn high-entropy spinel (HES) nanosheets on nickel foam (NF) by one-step solvothermal method, which exhibit an overpotential (eta 10) of only 188 mV at 10 mA cm-2, much lower than bimetallic CoFeOx/NF (233 mV), trimetallic CoFeCrOx/NF (211 mV), and tetrametallic CoFeCrMoOx/NF (200 mV). The OER overpotential decreases with the increase of the number of metals, indicating that the formation of HES has a positive effect on the improvement of electrocatalytic performance, since the synergistic effect between different metals enhances the charge transfer rate and decreases reaction barrier. In-situ Raman spectra demonstrate that the formation of gamma-NiOOH on the HES surface is a crucial active species for the OER. This work demonstrates a simple and efficient synthesis method to prepare nanoflower-like high-entropy electrocatalysts for efficient OER electrocatalysis. Nanoflower-like high-entropy CoFeCrMoMnOx/NF spinel catalyst exhibits outstanding electrocatalytic OER activity with an ultralow overpotential of 188 mV, surpassing most multicomponent electrocatalysts reported previously due to the synergistic effect between different metal elements. In-situ Raman spectra illustrate that the formation of gamma-NiOOH on the high-entropy spinel surface is a crucial active species for the OER. image