Reactivity of Olefin Functionalities of Dicyclopentadiene in the Diels-Alder Reaction with Thionylaniline

被引：0

作者：

Ilyushkina, E. K. ^{[1
]}

Veremeychik, Ya. V. ^{[1
]}

Lodochnikova, O. A. ^{[2
]}

Plemenkov, V. V. ^{[3
]}

机构：

[1] I Kant Balt Fed Univ, Kaliningrad 236040, Russia

[2] Russian Acad Sci, AE Arbuzov Inst Organ & Phys Chem, Fed Res Ctr Kazan Sci Ctr, Kazan 420088, Russia

[3] Kazan Fed Volga Reg Univ, AM Butlerov Inst Chem, Kazan 420008, Russia

来源：

RUSSIAN JOURNAL OF GENERAL CHEMISTRY | 2023年 / 93卷 / 05期

关键词：

sulfonamides; Diels-Alder reaction; co-crystallization; CYCLOPENTADIENE;

D O I：

10.1134/S1070363223050018

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reaction of thionylaniline with dicyclopentadiene has afforded the Diels-Alder adduct which has been oxidized into the corresponding sulfonamide bearing a benzothiazine moiety. Molecular and crystal structure of the sulfonamide has been elucidated via single-crystal X-ray diffraction analysis. Higher reactivity of the olefin functionality of the norbornene fragment has been found; the formation of two structural isomers has been revealed.

引用

页码：1019 / 1022

页数：4

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