At small incidence angles the dominant microwave backscattering mechanism is quasi-specular. In this case, reflection occurs from facets of the wave profile oriented perpendicular to the incident electromagnetic waves. A new theoretical algorithm was developed for determining the mean square slopes ( mss) of large-scale, in comparison with radar wavelength, sea waves from the azimuthal dependence of the backscattering radar cross section (RCS). In this paper the results of an experiment on measuring the azimuthal dependence of the backscattering RCS during the experiment on the Oka River within the city of Nizhny Novgorod is discussed. For measurements, two Ka-band radars installed on the metro bridge were used. To determine the mss of large-scale waves, the azimuthal dependence of the RCS, measured at one incidence angle was used. The comparison of the mss retrieved by the new algorithm, with the results of processing by the well-known algorithm using the dependence of the RCS on the incidence angle, confirmed the effectiveness of the new approach.