Synthesis and Properties of Metal Complexes with Halogen-Substituted Octaphenyltetraazaporphyrins

被引：1
|
作者：
Chizhova, N. V. [1 ]
Likhonina, A. E. [1 ]
Mamardashvili, N. Z. [1 ]
机构：
[1] Russian Acad Sci, GA Krestov Inst Solut Chem, Ivanovo 153040, Russia
来源：
RUSSIAN JOURNAL OF GENERAL CHEMISTRY | 2023年 / 93卷 / 06期
关键词：
complexes with octa-(4-halophenyl)tetraazaporphyrins; cyclomerization reactions; metal exchange reactions; photochemical stability; PORPHYRAZINE;
D O I：
10.1134/S1070363223060154
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
By reactions of di(4-halophenyl)maleindinitriles with magnesium and zinc(II) acetates in boiling ethylene glycol, Mg(II)-octa-(4-chlorophenyl)tetraazaporphyrin, Mg(II)-octa-(4-fluorophenyl)-tetraazaporphyrin, Zn(II)-octa-(4-chlorophenyl)tetraazaporphyrin, and Zn(II)-octa-(4-fluorophenyl)tetraazaporphyrins were synthesized. The cyclomerization of diphenylmaleinitrile with zinc acetate in ethylene glycol resulted in Zn(II)-Octaphenyltetraazaporphyrin. The corresponding Cu(II) and Mn(III)-octaphenyltetraazaporphyrins were synthesized in dimethylformamide using the metal exchange reaction of halogen-substituted magnesium complexes with copper(II) and manganese(II) chlorides. The obtained compounds were identified by electron absorption, IR, and H-1 NMR spectroscopy, and mass spectrometry. The photochemical stability of the synthesized complexes was studied.
引用
收藏
页码：1433 / 1439
页数：7
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