Mercury contamination in the water and sediments of a typical inland river - Lake basin in China: Occurrence, sources, migration and risk assessment

In the area affected by non-ferrous metal mining activities, mercury (Hg) contamination in the water and sed-iments posed potential risks to ecology and human health. In this study, river water and sediment samples were collected in the Zijiang river -South Dongting Lake basin to analyze Hg residues, identify potential Hg sources and evaluate the ecological and health risks posed by Hg contamination. In this study, the average concentrations of THg, PHg, DHg and DMeHg in river water were 38.05 +/- 27.13 ng/L, 25.18 +/- 26.83 ng/L, 12.88 +/- 9.64 ng/L and 0.29 +/- 0.07 ng/L, respectively. The THg and MeHg contents in sediments were 234.24 +/- 152.93 mu g/kg and 0.48 +/- 0.16 mu g/kg, respectively. The more enrichment of Hg in sediments was observed in the Zijiang River than in the South Dongting Lake, especially in the upstream and midstream regions. Two potential Hg sources in the basin were identified by correlation matrix, principal component analysis (PCA) and positive matrix factorization (PMF) model. The comparable Hg flux with other rivers worldwide was found in the Zijiang River (0.53 Mg/y). Furthermore, it was found by the delayed geochemical hazard (DGH) model that the ecological risk of Hg was more significant in the Zijiang River with more frequent transformation pathways. For different populations, the health risk values caused by Hg were all lower than the USEPA's guideline value. This study provided sound evidence for further control of Hg contamination.