Long-chain tin(iv) alkanethiolates (Sn(SCnH2n+1)4, n ≥ 12) with the coexistence of trans and gauche S-C bonds: a class of lamellar van der Waals molecular crystals

被引：3

作者：

Wang, Tingting ^{[1
]}

Wan, Yixin ^{[1
]}

Yu, Nan ^{[1
]}

Gu, Kewei ^{[1
]}

Lu, Zhiwei ^{[1
]}

Wang, Junli ^{[1
]}

机构：

[1] Jiangsu Univ, Sch Mat Sci & Engn, Zhenjiang 212013, Peoples R China

来源：

CRYSTENGCOMM | 2023年 / 25卷 / 41期

基金：

中国博士后科学基金;

关键词：

SULFIDE THIN-FILMS; NORMAL-ALKANES; ROTATOR PHASES; DEPOSITION;

D O I：

10.1039/d3ce00818e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Single-crystal XRD crystallography discloses a new class of vdWs molecular crystals, long-chain tin(IV) alkanethiolates (Sn(SCnH2n+1)(4), n >= 12). They exhibit a lamellar structure formed from molecular self-assembly due to the vdWs interactions of long all-trans alkyl chains, a nearly planar and rigid molecular geometry resulting from the coexistence of two trans and two gauche S-C bonds, and a variety of chain-length dependent physicochemical properties.

引用

页码：5782 / 5786

页数：5