Carbon Dioxide Conversion on Supported Metal Nanoparticles: A Brief Review

The increasing concentration of anthropogenic CO2 in the air is one of the main causes of global warming. The Paris Agreement at COP 21 aims to reach the global peak of greenhouse gas emissions in the second half of this century, with CO2 conversion towards valuable added compounds being one of the main strategies, especially in the field of heterogeneous catalysis. In the current search for new catalysts, the deposition of metallic nanoparticles (NPs) supported on metal oxides and metal carbide surfaces paves the way to new catalytic solutions. This review provides a comprehensive description and analysis of the relevant literature on the utilization of metal-supported NPs as catalysts for CO2 conversion to useful chemicals and propose that the next catalysts generation can be led by single-metal-atom deposition, since in general, small metal particles enhance the catalytic activity. Among the range of potential indicators of catalytic activity and selectivity, the relevance of NPs' size, the strong metal-support interactions, and the formation of vacancies on the support are exhaustively discussed from experimental and computational perspective.