Heterostructured Ultrathin Two-Dimensional Co-FeOOH Nanosheets@1D Ir-Co(OH)F Nanorods for Efficient Electrocatalytic Water Splitting

It is highly desirable to develop high-performance and robust electrocatalysts for overall water splitting, as the existing electrocatalysts exhibit poor catalytic performance toward hydrogen and oxygen evolution reactions (HER and OER) in the same electrolytes, resulting in high cost, low energy conversion efficiency, and complicated operating procedures. Herein, a heterostructured electrocatalyst is realized by growing Co-ZIF67-derived 2D Co-doped FeOOH on 1D Ir-doped Co(OH)F nanorods, denoted as Co-FeOOH@Ir-Co(OH)F. The Ir-doping couples with the synergy between Co-FeOOH and Ir-Co(OH)F effectively modulate the electronic structures and induce defect enriched interfaces. This bestows Co-FeOOH@Ir-Co(OH)F with abundant exposed active sites, accelerated reaction kinetics, improved charge transfer abilities, and optimized adsorption energies of reaction intermediates, which ultimately boost the bifunctional catalytic activity. Consequently, Co-FeOOH@Ir-Co(OH)F exhibits low overpotentials of 192/231/251 and 38/83/111 mV at current densities of 10/100/250 mA cm-2 toward the OER and HER in a 1.0 M KOH electrolyte, respectively. When CoFeOOH@Ir-Co(OH)F is used for overall water splitting, cell voltages of 1.48/1.60/1.67 V are required at current densities of 10/ 100/250 mA cm-2. Furthermore, it possesses outstanding long-term stability for OER, HER, and overall water splitting. Our study provides a promising way to prepare advanced heterostructured bifunctional electrocatalysts for overall alkaline water splitting.