Rapid naked eye sensing of fluoride by calix[4]arene upper rim tetra functionalized pentafluorophenyl hydrazone

被引：0
|
作者：
Nehra, Anita [1 ,2 ]
Malik, Apoorva [1 ]
Sharma, Pragati R. [1 ]
Bandaru, Sateesh [3 ]
Sharma, Rakesh K. [1 ]
机构：
[1] Indian Inst Technol Jodhpur, Dept Chem, Sustainable Mat & Catalysis Res Lab SMCRL, Jodhpur 342037, India
[2] JECRC Univ, Dept Chem, Sitapura Extens, Jaipur 303905, India
[3] Hangzhou Dianzi Univ, Coll Mat & Environm Engn, Hangzhou 310018, Peoples R China
来源：
NEW JOURNAL OF CHEMISTRY | 2023年 / 47卷 / 28期
关键词：
ANION RECOGNITION; RECEPTORS; CYANIDE;
D O I：
10.1039/d3nj02254d
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A neutral electron-deficient, pentafluorophenyl hydrazone-functionalized calix[4]arene, R, showed naked eye detection of fluoride among 19 anions. The formation of R + F- was evidenced by UV-vis, H-1 & F-19 NMR and ESI-MS studies. Variable temperature NMR studies revealed the formation of HF2-. DFT and TD-DFT studies demonstrate strong binding interactions between the R and F-.
引用
收藏
页码：13080 / 13083
页数：4
相关论文
共 50 条
  • [1] Colorimetric and fluorimetric chemosensor based on upper rim-functionalized calix[4]arene for selective detection of fluoride ion
    Nemati, Mohammad
    Hosseinzadeh, Rahman
    Mohadjerani, Maryam
    SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 2021, 245
  • [2] Synthesis of upper rim calix[4]arene carcerands
    Kuhnert, Nikolai
    Le-Gresley, Adam
    TETRAHEDRON LETTERS, 2008, 49 (07) : 1274 - 1276
  • [3] Stereoselective Synthesis of Lower and Upper Rim Functionalized Tetra-α Isomers of Calix[4]pyrroles
    Diaz-Moscoso, Alejandro
    Hernandez-Alonso, Daniel
    Escobar, Luis
    Arroyave, Frank A.
    Ballester, Pablo
    ORGANIC LETTERS, 2017, 19 (01) : 226 - 229
  • [4] A [2]catenane containing an upper-rim functionalized calix[4]arene for anion recognition
    Phipps, Dale E.
    Beer, Paul D.
    TETRAHEDRON LETTERS, 2009, 50 (26) : 3454 - 3457
  • [5] FUNCTIONALIZATION OF CALIX[4]ARENE WITH HYDROXYALKYL GROUPS AT UPPER RIM
    HWANG, KL
    HAM, SH
    NO, KH
    BULLETIN OF THE KOREAN CHEMICAL SOCIETY, 1993, 14 (01) : 79 - 81
  • [6] Shape-Persistent Oxa- and Aza-calix[4]arene Hybrid Molecular Cage and Naked Eye Sensing of Fluoride
    Li, Yong-Xue
    Xue, Min
    Yang, Yong
    ORGANIC LETTERS, 2021, 23 (16) : 6435 - 6438
  • [7] Selective Mono-dealkylation of Tetra-p-tert-butyl-calix[4]arene at the Upper Rim
    Berthalon, S.
    Regnouf de Vains, J.-B.
    Lamartine, R.
    Synthetic Communications, 26 (16):
  • [8] EXTENSION OF THE HYDROPHOBIC CAVITY OF CALIX[4]ARENE BY UPPER RIM FUNCTIONALIZATION
    ARDUINI, A
    POCHINI, A
    RIZZI, A
    SICURI, AR
    UGOZZOLI, F
    UNGARO, R
    TETRAHEDRON, 1992, 48 (05) : 905 - 912
  • [9] Synthesis of calix[4]arene library substituted with peptides at the upper rim
    Hioki, H
    Ohnishi, Y
    Kubo, M
    Nashimoto, E
    Kinoshita, Y
    Samejima, M
    Kodama, M
    TETRAHEDRON LETTERS, 2004, 45 (03) : 561 - 564
  • [10] SYNTHESIS OF A NEW RECEPTOR-BASED ON UPPER RIM FUNCTIONALIZED CALIX[5]ARENE
    HAINO, T
    HARANO, T
    MATSUMURA, K
    FUKAZAWA, Y
    TETRAHEDRON LETTERS, 1995, 36 (32) : 5793 - 5796
12345