Surface hardening through oxygen diffusion in niobium: The defining role of stress inhomogeneity in tensile embrittlement

Surface hardening, through oxygen diffusion, enforced significant tensile embrittlement of a commercial niobium (Nb) alloy (C-103). This was explored with microscopic digital image correlation and crystal plasticity finite element (CPFE) modeling. In particular, the presence of an oxygen-rich surface layer provided a gradient in hardness and elastic stiffness. These coincided with an increase in yield and tensile strength but a significant drop in ductility. The latter was reflected in the strain localization(s) and crack(s) on the hard gauge region, which ultimately led to a brittle failure. Full-field CPFE simulations were conducted on the actual microstructures. Our model, without crack and damage initiation, predicted extreme stress inhomogeneity during the tensile deformation. In brief, -5 times higher stress concentration was noted in the oxygen-rich hard surface grains. This appeared to be responsible for the subsequent crack initiation and embrittlement.