Compatibility of mesophase pitch and linear low-density polyethylene for low-cost carbon fiber

被引:3
|
作者
Scherschel, Alexander [1 ]
Love-Baker, Cole [1 ]
Sushchenko, Andre [1 ]
Harrell, Timothy [1 ]
Brown, Kenneth [1 ]
Li, Xiaodong [1 ]
机构
[1] Univ Virginia, Dept Mech & Aerosp Engn, 122 Engineers Way, Charlottesville, VA 22904 USA
关键词
Mesophase pitch; Polyethylene; Carbon fibers; Melt spun blended precursor; Microstructure; Mechanical properties; HIGH-STRENGTH; COAL-TAR; OXIDATIVE STABILIZATION; RAMAN-SPECTROSCOPY; PRECURSOR; MICROSTRUCTURE; CARBONIZATION; COMPOSITES;
D O I
10.1007/s10965-023-03466-3
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Mesophase pitch and linear low-density polyethylene (LLDPE) were blended by shear mixing and extruded producing precursor fibers which were then converted to carbon fibers (CFs). LLDPE additives agglomerate within the isotropic spheres rather than uniformly dispersing throughout the entire matrix. The blends possess different thermal properties and precursor tensile properties evident by two-phase tensile stress nature not present in precursor fibers produced from pure pitch. The resultant CFs were oxidized at 280 degrees C for 4 h and carbonized at 1000 degrees C for 15 min. This process created pitch CFs with a tensile strength of 1.23 GPa and a Young's modulus of 99 GPa. All CFs produced from blends of pitch and LLDPE possessed a tensile strength of 0.63 GPa and less. These CFs showed a microstructure slightly different from the pure pitch CFs with fractured CF cross sections revealing voids present in all blended CFs due to burnt off LLDPE stemming from carbonization. Further study into compatibilizers and new conversion processes is required to successfully blend LLDPE with mesophase pitch for the purpose of producing a new low-cost CF.
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页数:11
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