Copper Pyrithione (CuPT)-Catalyzed Oxidation of Secondary and Primary Benzyl Alcohols with Molecular oxygen or Air Under Mild Conditions

被引：1

作者：

Peng, Qionghui ^{[1
]}

Song, Bao ^{[1
,2
]}

Sun, Ningwen ^{[1
]}

Zhou, Xuehao ^{[1
,2
]}

Gong, Shaofeng ^{[1
]}

Xie, Jianwei ^{[1
]}

机构：

[1] Hunan Univ Sci & Engn, Coll Chem & Bioengn, Yongzhou 425199, Peoples R China

[2] Shihezi Univ, Sch Chem & Chem Engn, Key Lab Green Proc Chem Engn Xinjiang Bingtuan, Shihezi 832003, Peoples R China

来源：

CATALYSIS LETTERS | 2023年 / 153卷 / 09期

基金：

中国国家自然科学基金;

关键词：

Copper pyrithione; Oxidation; Green oxidant; Secondary and primary benzyl alcohols; Ketones and aldehydes; COPPER(I)/TEMPO CATALYST SYSTEM; AEROBIC OXIDATION; SELECTIVE OXIDATION; CARBOXYLIC-ACIDS; ALDEHYDES; EFFICIENT; METAL; WATER; KETONES; TEMPO;

D O I：

10.1007/s10562-022-04172-3

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Copper pyrithione was used for the first time as the catalyst for oxidation secondary and primary benzyl alcohols to furnish corresponding carbonyl compounds in high yields of up to 98%. This type of reactions can be carried out in mild conditions, using molecular oxygen or air as the oxidant, and exhibiting a wide substrate scopes and selectivity.

引用

页码：2665 / 2673

页数：9

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