Spectroscopic and Crystallographic Characterization of Two Hydrochloride Cathinones: 1-(4-fluoro-3-methylphenyl)-2-(pyrrolidin-1-yl)pentan-1-one (4-F-3-Me-α-PVP) and N-ethyl-2-amino-1-phenylheptan-1-one (N-ethylheptedrone)

被引：1

作者：

Rojkiewicz, Marcin ^{[1
,2
]}

Kus, Piotr ^{[1
]}

Kusz, Joachim ^{[3
]}

Ksiazek, Maria ^{[3
]}

Staszek, Dorota ^{[4
]}

机构：

[1] Univ Silesia, Inst Chem, 9 Szkolna St, PL-40006 Katowice, Poland

[2] Analyt Criminalist Lab FedaLab, 18-1A Fredry St, PL-40662 Katowice, Poland

[3] Univ Silesia, A Chelkowski Inst Phys, 1,75 Pulku Piechoty St, PL-41500 Chorzow, Poland

[4] Polish Acad Sci, Inst Organ Chem, 44-52 Kasprzaka St, PL-01224 Warsaw, Poland

来源：

CRYSTALS | 2023年 / 13卷 / 06期

关键词：

cathinones; 4F-3Me-& alpha; -PVP; N-ethylheptedrone; X-ray crystallography; mass spectrometry; NMR spectroscopy; SYNTHETIC CATHINONES; KHAT; DRUG;

D O I：

10.3390/cryst13060934

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

In this paper, two cathinone derivatives, 4F-3Me-a-PVP and N-ethylheptedrone, seized on the illegal drug market in Poland, were described and characterized by various instrumental analytical methods. The compounds were characterized by electrospray ionization mass spectrometry, high-resolution mass spectrometry, gas chromatography-mass spectrometry, infrared spectroscopy, X-ray crystallography, thermogravimetric analysis, differential scanning calorimetry and nuclear magnetic resonance spectroscopy. The two tested compounds were confirmed as 1-(4-fluoro-3-methylphenyl)-2-(pyrrolidin-1-yl)pentan-1-one and N-ethyl-2-amino-1-phenylheptan-1-one hydrochlorides; both are cathinone derivatives available on the market for new psychoactive substances (NPS). The obtained analytical data should be useful for forensic and toxicological purposes in the rapid and reliable identification of compounds.

引用

页数：17

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