Anthriporphyrinoids: Design, Synthesis, and Reactivity towards Diels-Alder Reaction

被引：3
|
作者：
Yadav, Bharti [1 ]
Ravikanth, Mangalampalli [1 ]
机构：
[1] Indian Inst Technol, Dept Chem, Mumbai 400076, India
来源：
JOURNAL OF ORGANIC CHEMISTRY | 2023年 / 88卷 / 13期
关键词：
FRAMEWORK; CHEMISTRY; SUBUNIT;
D O I：
10.1021/acs.joc.3c00953
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A series of non-aromatic anthripentaphyrinscontaining an anthraceneunit, two thiophenes, and two pyrrole rings as a part of a macrocyclicframework connected via three meso-carbons were synthesized.The crystal structure of one of the anthripentaphyrins revealed thatthe two thiophene rings were in an inverted orientation, and the macrocycleadopts a nonplanar Z-like ruffled structure. These anthriporphyrinoidsact as dienes and undergo Diels-Alder reaction with dienophilesto form stable non-aromatic Diels-Alder adducts.
引用
收藏
页码：9343 / 9351
页数：9
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