Oat straw pyrolysis with ammonium chloride doping: Analysis of evolved gases, kinetic triplet, and thermodynamic parameters

The purpose of this work was to determine the effect of the addition of NH4Cl to oat straw on the evolved gases, kinetic triplet, and thermodynamic parameters of the pyrolysis process at 873 K. A complementary approach allowed to assess the effects of the pyrolysis of chlorine-and nitrogen-enriched biomass. The thermal analysis of biomass was performed for four heating rates (5, 10, 20, and 30 K/min). The doping of NH4Cl in the straw favoured i) carbonisation of the chars, ii) formation of C-N bonds, iii) reduction of evolved CH4 and CO2, and iv) an increase in the mean values of the effective activation energy and all thermodynamic parameters. A group of reactions that best fit the experimental data of the pyrolysis process was selected. It was necessary to use un-specified mechanisms to describe the reaction model, particularly for samples enriched with NH4Cl.