Mathematical Processing of Experimental Data Obtained with Ampoule and Titration Calorimeters Equipped with Different Types of Cells

被引：0

作者：

Meshkov, A. N. ^{[1
]}

Gamov, G. A. ^{[1
]}

机构：

[1] Ivanovo State Univ Chem & Technol, Ivanovo 153000, Russia

来源：

RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY A | 2023年 / 97卷 / 02期

关键词：

calorimetry; equilibrium constant; change in enthalpy; EQUILIBRIUM-CONSTANTS; STANDARD ENTHALPIES; L-GLUTATHIONE; THERMODYNAMICS; COMPLEXATION; SYSTEMS; WATER; GD3+; ACID;

D O I：

10.1134/S0036024423020164

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

An algorithm is described for calculating the equilibrium constants and changes in the enthalpy of chemical reactions according to data from a calorimetric experiment performed on instruments of different types. Freeware is developed that executes the described algorithm. Differences from existing computer programs with similar functionality are briefly discussed, along with different statistical criteria of maximum likelihood.

引用

页码：323 / 327

页数：5

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