One-pot gram-scale rapid synthesis of MN4 complexes with 14-membered ring macrocyclic ligand as a precursor for carbon-based ORR and CO2RR catalysts

被引：0

作者：

Ogawa, Mana ^{[1
]}

Usami, Sayaka ^{[1
]}

Takahama, Ryo ^{[1
]}

Iwamoto, Kazuko ^{[1
]}

Nabeta, Tomomi ^{[1
]}

Kawashima, Shin ^{[2
]}

Kojima, Ryoichi ^{[2
]}

Ohyama, Junya ^{[3
]}

Hayakawa, Teruaki ^{[4
]}

Nabae, Yuta ^{[4
]}

Moriya, Makoto ^{[1
,5
,6
]}

机构：

[1] Shizuoka Univ, Grad Sch Integrated Sci & Technol, Dept Sci, 836 Ohya,Suruga Ku, Shizuoka 4228529, Japan

[2] Asahi Kasei Corp, Corp Res & Dev, 2767-11 Niihama, Kurashiki, Okayama 7118510, Japan

[3] Kumamoto Univ, Fac Adv Sci & Technol, 2-39-1 Kurokami,Chuo Ku, Kumamoto 8608555, Japan

[4] Tokyo Inst Technol, Dept Mat Sci & Engn, 2-12-1 S8-26 Ookayama,Meguro Ku, Tokyo 1528552, Japan

[5] Shizuoka Univ, Acad Inst, Coll Sci, 836 Ohya,Suruga Ku, Shizuoka 4228529, Japan

[6] Shizuoka Univ, Res Inst Green Sci & Technol, 836 Ohya,Suruga Ku, Shizuoka 4228529, Japan

来源：

DALTON TRANSACTIONS | 2024年 / 53卷 / 10期

关键词：

COBALT PHTHALOCYANINE; MOLECULAR-STRUCTURE; CRYSTAL-STRUCTURE; DIFFRACTION; REDUCTION; SITES; ALPHA;

D O I：

10.1039/d3dt04129h

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Herein, CoN4, CuN4, and NiN4 complexes with a 14-membered ring hexaazamacrocycle ligand H2HAM were synthesised as precursors for ORR and CO2RR catalysts via a one-pot, gram-scale synthesis procedure, which involved microwave heating for only 10 min. Detailed structures of the obtained 14MR-MN4 complex were revealed by single-crystal X-ray diffraction measurements.

引用

页码：4426 / 4431

页数：7