Pd-Complexes with Azanediylbis(1,2-azolyl)- and Bis(1,2-azolyl)carboxamide Ligands for Catalysis of Cross-Coupling Reactions in Aqueous Media

被引：0
|
作者：
Bumagin, N. A. [1 ]
Potkin, V. I. [2 ]
Zvereva, T. D. [2 ]
Kolesnik, I. A. [2 ]
机构：
[1] Lomonosov Moscow State Univ, Moscow 119991, Russia
[2] Natl Acad Sci Belarus, Inst Phys Organ Chem, Minsk 220072, BELARUS
来源：
RUSSIAN JOURNAL OF GENERAL CHEMISTRY | 2023年 / 93卷 / SUPPL 1期
基金：
俄罗斯基础研究基金会;
关键词：
1,2-azole; azanediylbis(1,2-azolyl)carboxamide; bis(1,2-azolyl)carboxamide; palladium; cross-coupling reactions; ORGANOMETALLIC COMPOUNDS; ORGANIC HALIDES; PALLADIUM; ACIDS;
D O I：
10.1134/S1070363223140104
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
5-Arylisoxazolyl- and 4,5-dichloroisothiazolyl-3-carboxamides were synthesized based on trichlorethylene and its dimer. The prepared carboxamides were used for the synthesis of azanediylbisisoxazolyl(isothiazolyl)carboxamides and bis(azolyl)carboxamides. The new polynitrogen ligands form palladium complexes LPdCl2, which exhibit high catalytic activity in cross-coupling reactions in water media in organic solvent-free conditions.
引用
收藏
页码：S31 / S41
页数：11
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