An Approach to Functionally Embellished o-Alkynylbenzoates or Furan-3(2H)-ones from Diynones and DMAD: Controlled Divergence and Product Selectivity

被引：10

作者：

Sarma, Manas Jyoti ^{[1
]}

Sudarshana, K. A. ^{[2
,3
]}

Mehta, Goverdhan ^{[1
]}

Srihari, Pabbaraja ^{[2
,3
]}

机构：

[1] Univ Hyderabad, Sch Chem, Hyderabad 500046, India

[2] CSIR Indian Inst Chem Technol, Dept Organ Synth & Proc Chem, Hyderabad 500007, India

[3] Acad Sci & Innovat Res AcSIR, Ghaziabad 201002, India

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2023年 / 88卷 / 06期

关键词：

CHEMISTRY;

D O I：

10.1021/acs.joc.2c02921

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The discovery of reaction regime controlled product diversification in a one-pot reaction between diynones and dimethyl-1,3-acetonedicarboxylate (DMAD) to selectively furnish either functionally unique pentasubstituted o-alkynylbenzoates or fully substituted furan-3(2H)-ones is delineated. The potential of these two versatile platforms to enter new utilitarian chemical space has also been explored.

引用

页码：3945 / 3953

页数：9