Pore-scale investigation on methane hydrate formation and plugging under gas-water flow conditions in a micromodel

被引:25
|
作者
Zhang, Jianbo [1 ,2 ]
Zhang, Ningtao [1 ]
Sun, Xiaohui [4 ]
Zhong, Jie [1 ]
Wang, Zhiyuan [1 ,2 ]
Hou, Lei [3 ]
Li, Shuxia [1 ]
Sun, Baojiang [1 ,2 ]
机构
[1] China Univ Petr East China, Sch Petr Engn, Qingdao 266555, Shandong, Peoples R China
[2] China Univ Petr East China, Key Lab Unconvent Oil & Gas Dev, Minist Educ, Qingdao 266580, Shandong, Peoples R China
[3] Univ Warwick, Sch Engn, Coventry CV4 7AL, England
[4] China Univ Petr East China, Coll Comp Sci & Technol, Qingdao 266580, Shandong, Peoples R China
基金
中国国家自然科学基金;
关键词
Hydrate formation; In -situ deposition; Pore channel; Gas-water flow; Micromodel; CARBON-DIOXIDE HYDRATE; POROUS-MEDIA; GROWTH; VISUALIZATION; DECOMPOSITION; KINETICS;
D O I
10.1016/j.fuel.2022.126312
中图分类号
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号
0807 ; 0820 ;
摘要
Hydrate formation in the pores of porous media is known to decrease reservoir permeability. Current research on hydrate formation in porous media primarily focuses on the static state. In this study, the formation and plugging of methane hydrate under gas-water flow conditions in a visible heterogeneous micromodel were investigated. The experimental results show that the hydrates formed in the pores tended to deposit in situ, and the intersection of different pore channels is critical for hydrate plugging in the micromodel. The higher the pressure in the pore channels, the higher the risk of hydrate formation and plugging. Meanwhile, the hydrate fraction in the pore channels was quantitatively analyzed to describe the hydrate formation and plugging behaviors, which are affected by the hydrate formation and dissolution processes. Based on the experimental results, the formation mechanism of hydrate plugging in microporous channels was proposed, which primarily includes four stages: formation of a water film by the gas-water flow, formation of a hydrate thin shell at the gas-water interface, hydrate deposition in situ and growth, and formation of hydrate plugging. This study establishes the experimental foundation for hydrate plugging prediction models and prevention methods for porous media.
引用
收藏
页数:12
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