Zinc Complexes Containing Substituted 1,10-Phenanthrolines as Ligands: Synthesis, Structure and Application as Initiators of ε-Caprolactone, Rac- and L-Lactides Polymerization

被引：0

作者：

Agaeva, M. U. ^{[1
,2
]}

Mankaev, B. N. ^{[1
,2
]}

Filippenko, V. I. ^{[2
]}

Lysenko, K. A. ^{[2
]}

Egorov, M. P. ^{[1
]}

Karlov, S. S. ^{[1
,2
]}

机构：

[1] Russian Acad Sci, ND Zelinsky Inst Organ Chem, Moscow 119991, Russia

[2] Lomonosov Moscow State Univ, Fac Chem, Moscow 119991, Russia

来源：

RUSSIAN JOURNAL OF GENERAL CHEMISTRY | 2023年 / 93卷 / SUPPL 1期

基金：

俄罗斯科学基金会;

关键词：

zinc; ligand; phenanthroline; ring-opening polymerization; RING-OPENING POLYMERIZATION;

D O I：

10.1134/S1070363223140426

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Zinc complexes X2Zn(L) (X = Et, OAc, OC(O)CF3)) were synthesized in which 1,10-phenanthrolines containing substituents at positions 2, 4, 7, and 9 were used as bidentate ligand L. The structures of the complexes were confirmed by NMR spectroscopy and elemental analysis. The structures of three complexes were investigated by X-ray diffraction analysis. The complexes have been studied as initiators of epsilon-caprolactone, L- and rac-lactides polymerization.

引用

页码：S304 / S316

页数：13

共 17 条

[1] Zinc Complexes Containing Substituted 1,10-Phenanthrolines as Ligands: Synthesis, Structure and Application as Initiators of ε-Caprolactone, Rac- and L-Lactides Polymerization
M. U. Agaeva
B. N. Mankaev
V. I. Filippenko
K. A. Lysenko
M. P. Egorov
S. S. Karlov
Russian Journal of General Chemistry, 2023, 93 : S304 - S316
[2] Aluminum complexes based on 1,10-phenanthroline-containing diols: synthesis and application as initiators of polymerization of ε-caprolactone
B. N. Mankaev
M. U. Agaeva
M. P. Egorov
S. S. Karlov
Russian Chemical Bulletin, 2022, 71 : 712 - 716
[3] Aluminum complexes based on 1,10-phenanthroline-containing diols: synthesis and application as initiators of polymerization of ε-caprolactone
Mankaev, B. N.
Agaeva, M. U.
Egorov, M. P.
Karlov, S. S.
RUSSIAN CHEMICAL BULLETIN, 2022, 71 (04) : 712 - 716
[4] Tetrylenes based on 1,10-phenanthroline-containing diol: the synthesis and application as initiators of ε-caprolactone polymerization
Mankaev, B. N.
Zaitsev, K. V.
Timashova, V. S.
Zaitseva, G. S.
Egorov, M. P.
Karlov, S. S.
RUSSIAN CHEMICAL BULLETIN, 2018, 67 (03) : 542 - 547
[5] Tetrylenes based on 1,10-phenanthroline-containing diol: the synthesis and application as initiators of ε-caprolactone polymerization
B. N. Mankaev
K. V. Zaitsev
V. S. Timashova
G. S. Zaitseva
M. P. Egorov
S. S. Karlov
Russian Chemical Bulletin, 2018, 67 : 542 - 547
[6] RUTHENIUM(II) COMPLEXES OF MODIFIED 1,10-PHENANTHROLINES .1. SYNTHESIS AND PROPERTIES OF COMPLEXES CONTAINING DIPYRIDOPHENAZINES AND A DICYANOMETHYLENE-SUBSTITUTED 1,10-PHENANTHROLINE
ACKERMANN, MN
INTERRANTE, LV
INORGANIC CHEMISTRY, 1984, 23 (24) : 3904 - 3911
[7] Zinc Complexes Supported by Maltolato Ligands: Synthesis, Structure, Solution Behavior, and Application in Ring-Opening Polymerization of Lactides
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ORGANOMETALLICS, 2012, 31 (13) : 4755 - 4762
[8] Group 3 Metal Complexes of Salen-like Fluorous Dialkoxy-Diimino Ligands: Synthesis, Structure, and Application in Ring-Opening Polymerization of rac-Lactide and rac-β-Butyrolactone
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Kirillov, Evgueni
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ORGANOMETALLICS, 2008, 27 (21) : 5691 - 5698
[9] Cubane-Type Polynuclear Zinc Complexes Containing Tridentate Schiff Base Ligands: Synthesis, Characterization, and Ring-Opening Polymerization Studies of rac-Lactide and ε-Caprolactone
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Spannenberg, Anke
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HELVETICA CHIMICA ACTA, 2017, 100 (11)
[10] Synthesis, Structure of Zinc Complexes Containing Sulfonylated Binaphtholate Ligands and Their Catalytic Activities towards Ring-Opening Polymerization of Lactide and e-Caprolactone
Zhou Shuangliu
Jiang Yongyao
Xie Tao
Wu Zhanshuan
Zhou Linmin
Xu Wenjing
Zhang Lijun
Wang Shaowu
CHINESE JOURNAL OF CHEMISTRY, 2012, 30 (09) : 2176 - 2182

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