Chirality-controlled spin scattering through quantum interference

被引:2
|
作者
van Ruitenbeek, Jan M. M. [1 ]
Korytar, Richard [2 ]
Evers, Ferdinand [3 ]
机构
[1] Leiden Univ, Huygens Kamerlingh Onnes Lab, NL-2333 CA Leiden, Netherlands
[2] Charles Univ Prague, Dept Condensed Matter Phys, Prague 2, Czech Republic
[3] Univ Regensburg, Inst Theoret Phys, D-93050 Regensburg, Germany
来源
JOURNAL OF CHEMICAL PHYSICS | 2023年 / 159卷 / 02期
关键词
DEPENDENT ELECTRON TRANSMISSION; MOLECULES; SELECTIVITY;
D O I
10.1063/5.0156316
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Chirality-induced spin selectivity has been reported in many experiments, but a generally accepted theoretical explanation has not yet been proposed. Here, we introduce a simple model system of a straight cylindrical free-electron wire containing a helical string of atomic scattering centers with spin-orbit interaction. The advantage of this simple model is that it allows deriving analytical expressions for the spin scattering rates, such that the origin of the effect can be easily followed. We find that spin-selective scattering can be viewed as resulting from the constructive interference of partial waves scattered by the spin-orbit terms. We demonstrate that forward scattering rates are independent of spin, while back scattering is spin dependent over wide windows of energy. Although the model does not represent the full details of electron transmission through chiral molecules, it clearly reveals a mechanism that could operate in chiral systems.
引用
收藏
页数:7
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