In situ rapid synthesis of ionic liquid/ionic covalent organic framework composites for CO2 fixation

被引：7

作者：

Xu, Zhifeng ^{[1
]}

Wang, Wenting ^{[1
]}

Chen, Bowei ^{[1
]}

Zhou, Haitao ^{[1
]}

Yao, Qiufang ^{[2
]}

Shen, Xianjie ^{[1
]}

Pan, Yuchen ^{[1
]}

Wu, Dongxian ^{[1
]}

Cao, Yongyong ^{[1
]}

Shen, Zhangfeng ^{[1
]}

Liu, Yanan ^{[1
]}

Xia, Qineng ^{[1
]}

Li, Xi ^{[1
]}

Zou, Xiaoqin ^{[3
]}

Wang, Yangang ^{[1
]}

Jiang, Lingchang ^{[1
]}

机构：

[1] Jiaxing Univ, Coll Biol Chem Sci & Engn, Jiaxing 314001, Zhejiang, Peoples R China

[2] Jiaxing Nanhu Univ, Coll Adv Mat Engn, 572 Yuexiu Rd, Jiaxing 314001, Peoples R China

[3] Northeast Normal Univ, Fac Chem, 5268 Renmin St, Changchun 130024, Jilin, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2023年 / 59卷 / 97期

基金：

中国国家自然科学基金;

关键词：

EFFICIENT SYNTHESIS; CYCLIC CARBONATES; STYRENE OXIDE;

D O I：

10.1039/d3cc04763f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

IL/ICOF composites were in situ synthesized via a one-pot route in half an hour under ambient conditions for catalytic cycloaddition of CO2 with epoxides into cyclic carbonates. The prepared composites feature a decent CO2 adsorption capacity of 1.63 mmol g(-1) at 273 K and 1 bar and exhibit excellent catalytic performance in terms of yield and durability. This work may pave a new way to design and construct functionalized porous organic frameworks as heterogeneous catalysts for CO2 capture and conversion.

引用

页码：14435 / 14438

页数：4

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