Electrophilic and nucleophilic gas phase reactivity of the Janus cluster-based anions [{Mo6Cl8}Cl5]- ( = lacuna)

被引：1

作者：

Denis, Antoine ^{[1
]}

Tyminska, Nina ^{[2
]}

Delhaye, Thomas ^{[1
]}

Molard, Yann ^{[2
]}

Gerbaux, Pascal ^{[3
]}

De Winter, Julien ^{[3
]}

Himdi, Mohamed ^{[1
]}

Castel, Xavier ^{[1
]}

Costuas, Karine ^{[2
]}

Cordier, Stephane ^{[2
]}

Rondeau, David ^{[1
]}

机构：

[1] Univ Rennes, Inst Elect, CNRS, Technol numeR UMR 6164, F-35000 Rennes, France

[2] Univ Rennes, Inst Sci Chim Rennes, UMR 6226, F-35000 Rennes, France

[3] Univ Mons, Interdisciplinary Ctr Mass Spectrometry CISMa, Organ Synth & Mass Spectrometry Lab, UMONS, 23 Pl Parc, B-7000 Mons, Belgium

来源：

CHEMICAL COMMUNICATIONS | 2023年 / 59卷 / 41期

关键词：

CELL;

D O I：

10.1039/d3cc01187a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The lacunary monocharged anion [{Mo(6)Cli(8)}Cla 5&a]- presents concomitantly a strongly electrophilic site and a nucleophilic one. This Janus character in terms of reactivity is confirmed by its gas phase reaction with [Br6Cs4K](-) to form [{Mo(6)Cli(8)}Cla(5)Bra](2-) and by its unusual self-reactivity leading to [{Mo(6)Cli(8)}Cla(6)]2- dianions.

引用

页码：6243 / 6246

页数：4

共 48 条

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