Incorporation of Ag-doped ZnO nanorod through Graphite hybridization: Effective approach for degradation of Ciprofloxacin

To remove the Ciprofloxacin (CIP) from aqueous solution, ZnO-Ag-Gp nanocomposite exhibited efficient photocatalytic properties. The biopersistent CIP is pervasive in surface water and also hazardous to human and animal health. This study utilized the hydrothermal technique to pre-pare Ag-doped ZnO hybridizing Graphite (Gp) sheet (ZnO-Ag-Gp) to degrade pharmaceuticals pollutant CIP from an aqueous medium. The structural and chemical compositions of the pho-tocatalysts were determined by XRD, FTIR and XPS analysis. FESEM and TEM images revealed the nanorod ZnO with round shape Ag distributed on a Gp surface. The reduced bandgap of the ZnO-Ag-Gp sample enhanced the photocatalytic property which was measured by using UV-vis Spectroscopy. Dose optimization study found that 1.2 g/L is optimum for single (ZnO) and binary (ZnO-Gp and ZnO-Ag), where 0.3 g/L ternary (ZnO-Ag-Gp) exhibited maximum degradation efficiency (98%) within 60 min for 5 mg/L CIP. Pseudo 1st order reaction kinetics rate was found highest for ZnO-Ag-Gp (0.05983 min -1) and it decreased to 0.03428 min -1 for annealed sample. Removal efficiency decreased to only 90.97% at 5th run and hydroxyl radicals played a vital role to degrade CIP from aqueous solution. UV/ZnO-Ag-Gp will be a promising technique to degrade wide-ranging pharmaceutical antibiotics from the aquatic medium.