Towards the design of self-sorting nanomaterials through kinetically directed chemoselective control over interfacial surface chemistry

被引:1
|
作者
Gunawardene, Praveen N. [1 ,2 ]
Weissman, Max [1 ,2 ]
Bowman, Jack E. [1 ,2 ]
Gobbo, Pierangelo [1 ,2 ,3 ]
Workentin, Mark S. [1 ,2 ]
机构
[1] Univ Western Ontario, Dept Chem, London, ON N6A 5B7, Canada
[2] Univ Western Ontario, Ctr Adv Mat & Biomat Res, London, ON N6A 5B7, Canada
[3] Univ Trieste, Dept Chem & Pharmaceut Sci, Trieste, Italy
关键词
Compilation and indexing terms; Copyright 2025 Elsevier Inc;
D O I
10.1039/d3tb00207a
中图分类号
TB3 [工程材料学]; R318.08 [生物材料学];
学科分类号
0805 ; 080501 ; 080502 ;
摘要
A gold nanoparticle platform is described in which post-synthesis surface modifications can be conducted using kinetically-tunable strain-promoted cycloaddition chemistry, which is dependent on the electronic properties of the complementary dipolar species. This permits chemoselective reactivity with one reactive dipole over another less reactive dipole, providing exciting opportinities for kinetically-directed self-sorting strategies.
引用
收藏
页码:4661 / 4665
页数:5
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