Understanding the pyrolysis kinetics, thermodynamic, and environmental sustainability parameters of Sesamum indicum crop residue

In this work, the physiochemical characteristics, thermodynamics, and sustainability of the pyrolysis of Sesamum indicum biomass were assessed. The pyrolysis kinetics of sesame agro-residues performed using isoconversional techniques such as Kissinger, KAS, and OFW methods showed activation energies of 192, 120, and 123 kJ mol(-1), respectively. The impact of the pyrolysis temperature (550, 650, 750 degrees C) on the generation of biochar, bio-oil, and gas is also studied; the exergy efficiency increased from 82.7 at 550 degrees C to 87.3% at 750 degrees C with an increase in the temperature. Sesame biochar's Van Krevalan diagram showed how its fuel-like characteristics also grew with rising temperatures. The input and output parameters showed a high agreement in the mass, energy, and exergy balance closures. However, it was shown that the overall energy efficiency was greater at 750 degrees C (71.2%) compared to 55.5% and 69.8% at 550 degrees C and 650 degrees C, respectively. Sustainability analysis showed that lower temperatures had a smaller impact on the environment.