Bis(N-tert-butylacetamido) (dimethylamido) (chloro)titanium

被引：0
|
作者：
Seth Jr, Dennis M. [1 ]
Waterman, Rory [1 ]
机构：
[1] Univ Vermont, Dept Chem, Burlington, VT 05405 USA
来源：
MOLBANK | 2024年 / 2024卷 / 01期
关键词：
titanium; amidate; crystal; AMIDATE COMPLEXES; HYDROPHOSPHINATION; CHALLENGES; TI;
D O I：
10.3390/M1786
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The titanium amidate compound bis(N-tert-butylacetamido)(dimethylamido)(chloro)titanium was synthesized by the protonolysis of tris(dimethylamido)(chloro)titanium and structurally characterized by H-1 and C-13 NMR spectroscopy as well as X-ray diffraction. The compound does not appear to react cleanly nor readily with routine alkylating agents such as sec-butyllithium, benzyl potassium, or trimethylsilyl methyllithium.
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页数：5
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