Insight the mechanism of MgAl/layered double hydroxide supported on rubber seed shell biochar for Remazol Brilliant Violet 5R removal

被引:8
|
作者
Anthonysamy, Shahreen Izwan [1 ]
Ahmad, Mohd Azmier [1 ]
Yahaya, Nasehir Khan E. M. [2 ]
机构
[1] Univ Sains Malaysia, Sch Chem Engn, Engn Campus, George Town 14300, Malaysia
[2] Natl Water Res Inst Malaysia NAHRIM, Minist Nat Resources Environm & Climate Change, Lot 5377,Jalan Putra Permai, Selangor 43300, Malaysia
关键词
Biochar; Remazol Brilliant Violet 5R; Rubber seed shell; Endothermic; Physisorption; LAYERED DOUBLE HYDROXIDES; HIGHLY EFFICIENT REMOVAL; TEXTILE WASTE-WATER; METHYLENE-BLUE; ADSORPTIVE REMOVAL; ACTIVATED CARBON; AQUEOUS-SOLUTION; PHOTOCATALYTIC DEGRADATION; FACILE SYNTHESIS; REACTIVE DYE;
D O I
10.1016/j.arabjc.2023.104643
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The ever-increasing concentration of Remazol Brilliant Violet 5R discharged mainly from textile industry had cause serious environmental issues towards human and the surrounding ecosystem. Therefore, solving the issue related to dye contamination is seriously important. In this research study, MgAl/layered double hydroxide supported on rubber seed shell biochar (RSSB) had been prepared for Remazol Brilliant Violet 5R (RBV5R) dye adsorption. BET surface area and pore volume of RSSB were found to be 132.40 m2/g and 0.0732 cm3/g, respectively with presence of LDH metals on the RSSB surfaces. The batch adsorption studies showed that RBV5R uptake capacity was significantly enhanced (125.88 mg/g) compared to pristine RSSB (58.69 mg/g) at initial RBV5R concentration, contact time, adsorption temperature and pH of 300 mg/l, 1440 min, 60 degrees C and pH 2, respectively. The equilibrium and kinetic adsorption data were best fitted into the Fre-undlich and pseudo-first order model, respectively. The thermodynamic study confirmed the RBV5R adsorption was endothermic in nature and governed by physisorption process. All these findings signified that the MgAl/LDH-RSSB is a promising adsorbent for treating wastewater con-taining RBV5R dye.(c) 2023 The Author(s). Published by Elsevier B.V. on behalf of King Saud University. This is an open access article under the CC BY license (http://creativecommons.org/licenses/by/4.0/).
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页数:27
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