H2O-HF dimer rotational spectra: New measurements and re-analysis

被引:1
|
作者
Golubiatnikov, German Yu. [1 ]
Polyansky, Oleg L. [1 ,2 ]
Zobov, Nikolai F. [1 ]
Tennyson, Jonathan [2 ]
Ovsyannikov, Roman I. [1 ]
Tretyakov, Mikhail Yu. [1 ]
机构
[1] Russian Acad Sci, Inst Appl Phys, 46 Ulyanov St, Nizhnii Novgorod 603950, Russia
[2] UCL, Dept Phys & Astron, Gower St, London WC1E 6BT, England
基金
英国自然环境研究理事会;
关键词
H2O-HF dimer; Millimeter and sub-millimeter wave spectra; High resolution; Rotational constants; HYDROGEN-BONDING INTERACTIONS; GAS-PHASE; SPECTROSCOPIC INVESTIGATIONS; SUBMILLIMETER SPECTRUM; WATER-VAPOR; MICROWAVE; FLUORIDE; HF; ABSORPTION;
D O I
10.1016/j.jms.2023.111836
中图分类号
O64 [物理化学(理论化学)、化学物理学]; O56 [分子物理学、原子物理学];
学科分类号
070203 ; 070304 ; 081704 ; 1406 ;
摘要
New measurements of the H2O-HF dimer high resolution absorption spectrum are performed using a relatively warm (240-260 K) equilibrium gas mixture with two complementary spectrometers: a video spectrometer and spectrometer with radio-acoustic detection. Positions of over hundred H2O-HF lines in the 158-345 GHz range are refined (their uncertainty is reduced by about order of magnitude) and several tens of lines are newly measured. These data are re-fitted together with previous measurements giving a refined set of constants of effective Hamiltonian which characterizes the dimer intermolecular dynamics. The new data improves significantly (from 100 to about 10 kHz) the accuracy of rotational constants corresponding to separate series of lines with fixed Ka.
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页数:8
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