Cs[B3O3F2(OH)2]: discovery of a hydroxyfluorooxoborate guided by selective organic-inorganic transformation

被引：8
|
作者：
Chen, Ziqi [1 ,2 ]
Li, Fuming [1 ,2 ]
Han, Jian [1 ,2 ]
Yang, Zhihua [1 ,2 ]
Pan, Shilie [1 ,2 ]
Mutailipu, Miriding [1 ,2 ]
机构：
[1] Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Res Ctr Crystal Mat, CAS Key Lab Funct Mat & Devices Special Environm, Urumqi, Peoples R China
[2] Univ Chinese Acad Sci, Ctr Mat Sci & Optoelect Engn, Beijing, Peoples R China
来源：
CHEMICAL COMMUNICATIONS | 2023年 / 59卷 / 15期
基金：
中国国家自然科学基金; 美国国家科学基金会; 国家重点研发计划;
关键词：
NONLINEAR-OPTICAL MATERIAL; CRYSTAL-STRUCTURE; DESIGN; ANIONS; OXIDES;
D O I：
10.1039/d2cc06924e
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Selective transformation between organic and inorganic systems is crucial but still remains a challenge. Herein, we demonstrated that selective organic-inorganic transformation is a simple but effective strategy to find new hydroxyfluorooxoborates. By replacing the [Ph4P]/[Ph3MeP] organic cations with Cs atoms, a new hydroxyfluorooxoborate Cs[B3O3F2(OH)(2)] with three-membered [B3O3F2(OH)(2)] clusters was synthesized. Theoretical analysis confirmed the effects of different components in the lattice of reported structure on the optical properties.
引用
收藏
页码：2114 / 2117
页数：4
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