Production of functional C4 organic acids from ammonolysis of biofeedstock poly(3-hydroxybutyrate)

被引：4
|
作者：
Peng, Zhezhe [1 ]
Yu, Donghai [2 ]
Fu, Jinxia [3 ]
Xu, Yongjun [1 ]
Kang, Shimin [1 ]
机构：
[1] Dongguan Univ Technol, Engn Res Ctr None Food Biomass Efficient Pyrolysi, Guangdong Prov Key Lab Distributed Energy Syst, Guangdong Higher Educ Inst, Dongguan 523808, Peoples R China
[2] Chinese Acad Sci, Univ Chinese Acad Sci, Shanghai Inst Organ Chem, Key Lab Organofluorine Chem, 345 Lingling Rd, Shanghai 200032, Peoples R China
[3] Univ Hawaii Manoa, Hawaii Nat Energy Inst, Honolulu, HI 96822 USA
来源：
BIOMASS CONVERSION AND BIOREFINERY | 2023年 / 13卷 / 04期
关键词：
Poly(3-hydroxybutyrate); Ammonolysis; β -Aminobutyric acid; -Hydroxybutyric acid; Crotonic acid; BETA-AMINOBUTYRIC ACID; (R)-3-HYDROXYBUTYRIC ACID; RESISTANCE; BIOMASS; DEFENSE; FRUIT;
D O I：
10.1007/s13399-021-01364-6
中图分类号：
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号：
0807 ; 0820 ;
摘要：
A new ammonolysis technology is developed for producing targeted functional C-4 acids from a renewable feedstock, i.e., poly(3-hydroxybutyrate) (PHB). beta-Aminobutyric acid (BABA) and beta-hydroxybutyric acid (BHBA) are produced from PHB with an aggregate selectivity of 99% under a one-pot catalyst-free reaction at 140 degrees C. The product distribution can be controlled by ammonia concentration, and the reaction mechanism is investigated based on quantum chemical calculation. This work establishes a promising route for the production of beta-substituted C-4 acids via a green and sustainable pathway.
引用
收藏
页码：2615 / 2621
页数：7
相关论文
共 50 条
  • [1] Production of functional C4 organic acids from ammonolysis of biofeedstock poly(3-hydroxybutyrate)
    Zhezhe Peng
    Donghai Yu
    Jinxia Fu
    Yongjun Xu
    Shimin Kang
    Biomass Conversion and Biorefinery, 2023, 13 : 2615 - 2621
  • [2] Ulva rigida Valorization into Poly(3-hydroxybutyrate), Organic Acids and Functional Ingredients
    Leandro, Tania
    Teles, Marco
    Gomes-Dias, Joana S.
    Marques, Mafalda
    Rocha, Cristina M. R.
    da Fonseca, M. Manuela R.
    Cesario, M. Teresa
    MARINE DRUGS, 2023, 21 (10)
  • [3] Production of poly(3-hydroxybutyrate) and poly(3-hydroxybutyrate-co-4-hydroxybutyrate) by Ralstonia eutropha from soybean oil
    Park, Dae Hoo
    Kim, Beom Soo
    NEW BIOTECHNOLOGY, 2011, 28 (06) : 719 - 724
  • [4] Production of poly(3-hydroxybutyrate) from inexpensive substrates
    Kim, BS
    ENZYME AND MICROBIAL TECHNOLOGY, 2000, 27 (10) : 774 - 777
  • [5] Production of poly(3-hydroxybutyrate) from molasses and peach pulp
    Kivanc, Merih
    Bahar, Hakan
    Yilmaz, Meral
    JOURNAL OF BIOTECHNOLOGY, 2008, 136 : S405 - S406
  • [6] Production of poly(3-hydroxybutyrate) from waste potato starch
    Haas, Richard
    Jin, Bo
    Zepf, Florian Tobias
    BIOSCIENCE BIOTECHNOLOGY AND BIOCHEMISTRY, 2008, 72 (01) : 253 - 256
  • [7] Production of poly (3-hydroxybutyrate) from starch by Azotobacter chroococcum
    Beom Soo Kim
    Ho Nam Chang
    Biotechnology Letters, 1998, 20 : 109 - 112
  • [8] Production of poly(3-hydroxybutyrate) from starch by Azotobacter chroococcum
    Kim, BS
    Chang, HN
    BIOTECHNOLOGY LETTERS, 1998, 20 (02) : 109 - 112
  • [9] Anaerobic Production of Poly(3-hydroxybutyrate) and Its Precursor 3-Hydroxybutyrate from Synthesis Gas by Autotrophic Clostridia
    Fluechter, Sebastian
    Follonier, Stephanie
    Schiel-Bengelsdorf, Bettina
    Bengelsdorf, Frank R.
    Zinn, Manfred
    Duerre, Peter
    BIOMACROMOLECULES, 2019, 20 (09) : 3271 - 3282
  • [10] Production of poly(3-hydroxybutyrate) by recombinant bacteria
    Lee, SY
    Choi, JI
    Wang, F
    SCIENCE AND TECHNOLOGY OF POLYMERS AND ADVANCED MATERIALS: EMERGING TECHNOLOGIES AND BUSINESS OPPORTUNITIES, 1998, : 463 - 475
12345