One year operation of an anion exchange membrane water electrolyzer utilizing Aemion+? membrane: Minimal degradation, low H2 crossover and high efficiency

被引:41
|
作者
Moreno-Gonzalez, Marta [1 ]
Mardle, Peter [2 ]
Zhu, Shan [1 ]
Gholamkhass, Bobak [1 ]
Jones, Scot [1 ]
Chen, Nathan [1 ]
Britton, Benjamin [1 ]
Holdcroft, Steven [2 ]
机构
[1] Ionomr Innovat Inc, 2386 East Mall, Vancouver, BC V6T 1Z3, Canada
[2] Simon Fraser Univ, Dept Chem, 8888 Univ Dr, Burnaby, BC V5A 1S6, Canada
来源
基金
加拿大自然科学与工程研究理事会;
关键词
Anion exchange membrane; Alkaline membrane water electrolyzer; Zero gap; Aemion; Reinforced membrane; Durability; CONDUCTING POLYMER; OXYGEN EVOLUTION; TEMPERATURE; HYDROGEN; ENERGY; PERFORMANCE; ELECTRODES; DEPENDENCE; STABILITY;
D O I
10.1016/j.powera.2023.100109
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Using a highly ion conductive, chemically stable, mechanically robust, reinforced anion exchange membrane (AEM) of nominal thickness 85 mu m, we report an AEM water electrolyzer operating for longer than one year at 70 degrees C with 1 M KOH electrolyte, with H2 crossover below industrial limits. The minimal degradation observed is due to the membrane-electrode-assembly and not due to the membrane, which exhibits negligible change in its ionic conductivity after >1 yr operation. A minimal hydrogen crossover from cathode to anode of <0.4% was also measured for a second cell running for 5000 h (>7 months). This study shows that future research towards zero gap alkaline water electrolyzers should be directed to the development of active and stable catalysts and the formation and integration of stable catalyst layers tailored to AEM water electrolyzers.
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页数:7
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