Influence of size and temperature on the auto-ignition characteristics of solid beech and spruce wood

被引:5
|
作者
Preimesberger, Christoph [1 ,3 ]
Solt-Rindler, Axel [1 ,3 ]
Hansmann, Christian [1 ,3 ]
Pfeifer, Christoph [2 ]
机构
[1] Kompetenzzentrum Holz GmbH, Wood K Plus Competence Ctr Wood Composites & Wood, Altenberger Str 69, A-4040 Linz, Austria
[2] Univ Nat Resources & Life Sci BOKU, Inst Chem & Energy Engn, Muthgasse 107-I, A-1190 Vienna, Austria
[3] Univ Nat Resources & Life Sci BOKU, Inst Wood Technol & Renewable Mat, Konrad Lorenz Str 24, A-3430 Tulln An Der Donau, Austria
关键词
Auto-ignition; simultaneous thermal analysis (STA); Size dependence; Solid wood; Pyrolysis; THERMAL-DECOMPOSITION; PARTICLE-SIZE; PYROLYSIS; CELLULOSE;
D O I
10.1016/j.fuel.2022.127140
中图分类号
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号
0807 ; 0820 ;
摘要
The influence of size and temperature on the heating and auto-ignition of beech (fagus sylvatica) and spruce (picea abies) wood cubes were studied. Experiments were conducted in a furnace at five isothermal temperatures (240 degrees C, 270 degrees C, 300 degrees C, 330 degrees C and 360 degrees C) with four cube sizes (5 mm, 10 mm, 15 mm and 20 mm). Tem-peratures inside the cubes were recorded with thermocouples (TC). Arising temperatures from the experiments were compared to mass-losses and exothermic reactions measured with simultaneous thermal analysis (STA). While heating up isothermal phases at approx. 360 degrees C can be seen in the temperature curves due to ongoing pyrolysis. After pyrolysis, a combination of internal heating and heterogenous oxidation reactions on the surface lead to ignition and combustion. Differences in chemical composition between beech and spruce are the cause for exothermic reactions at lower temperatures. Bigger samples tend to ignite at lower temperatures due to lower surface to volume ratio and a larger reactive surface.
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页数:8
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