High-Power-Density and High-Energy-Efficiency Zinc-Air Flow Battery System for Long-Duration Energy Storage

被引:8
|
作者
Zhao, Siyuan [1 ,2 ]
Liu, Tong [1 ,2 ]
Zuo, Yayu [3 ]
Wei, Manhui [3 ]
Wang, Jian [4 ]
Shao, Zongping [5 ,6 ]
Leung, Dennis Y. C. [7 ]
Zhao, Tianshou [8 ]
Ni, Meng [1 ,2 ]
机构
[1] Hong Kong Polytech Univ, Res Inst Sustainable Urban Dev RISUD, Dept Bldg & Real Estate, Hung Hom,Kowloon, Hong Kong, Peoples R China
[2] Hong Kong Polytech Univ, Res Inst Smart Energy RISE, Hung Hom, Kowloon, Hong Kong, Peoples R China
[3] Beijing Inst Technol, Sch Mech Engn, Beijing 100081, Peoples R China
[4] City Univ Hong Kong, Sch Energy & Environm, Hong Kong, Peoples R China
[5] Nanjing Tech Univ, Coll Chem Engn, State Key Lab Mat Oriented Chem Engn, Nanjing 211816, Peoples R China
[6] Curtin Univ, WA Sch Mines Minerals Energy & Chem Engn WASM MECE, Perth, WA 6854, Australia
[7] Univ Hong Kong, Dept Mech Engn, Pokfulam Rd, Hong Kong, Peoples R China
[8] Southern Univ Sci & Technol, Coll Engn, Dept Mech & Energy Engn, Shenzhen 518055, Peoples R China
关键词
Acid-alkaline electrolyte; High discharge voltage; Long-duration energy storage; Low charging voltage; Zinc-air flow battery; FUEL-CELL; REGENERATION; ELECTROLYSIS; CHALLENGES; DEPOSITION; MORPHOLOGY;
D O I
10.1016/j.cej.2023.144091
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
To achieve long-duration energy storage (LDES), a technological and economical battery technology is imperative. Herein, we demonstrate an all-around zinc-air flow battery (ZAFB), where a decoupled acid-alkaline electrolyte elevates the discharge voltage to -1.8 V, and a reaction modifier KI lowers the charging voltage to -1.8 V. This ZAFB exhibits a long discharge duration of over 4 h, a high power density of 178 mW cm-2 (about 76 % higher than conventional ZAFB), and unprecedented energy efficiency of nearly 100 %. Moreover, the ZAFB demonstrates outstanding fast charging ability, mitigated zinc dendrite growth and parasitic hydrogen evolution, enhanced cathode protection, and good resistance to environmental disturbance. This all-around ZAFB will not only become a very promising option for LDES but also promote the development of other LDES systems.
引用
收藏
页数:9
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