Insights into the use of green leaching systems based on glycine for the selective recovery of copper

被引:6
|
作者
Barragan-Mantilla, S. P. [1 ,2 ]
Gasco, G. [2 ]
Almendros, P. [3 ]
Mendez, A. [1 ,4 ]
机构
[1] Univ Politecn Madrid, Mines & Energy Sch, Dept Geol & Min Engn, Madrid 28040, Spain
[2] Univ Politecn Madrid, Agron Food & Biosyst Engn Sch, Dept Agr Prod, Madrid 28040, Spain
[3] Univ Politecn Madrid, Chem & Food Technol Dept, CEIGRAM, Res Ctr Management Agr & Environm Risks, Madrid 28040, Spain
[4] Univ Politecn Madrid, Mines & Energy Sch, Dept Geol & Min Engn, Madrid, Spain
关键词
Hydrometallurgy; Copper; Arsenic; Leaching; Glycine; HYDROGEN-PEROXIDE; AMINO-ACIDS; ALKALINE; CONCENTRATE; GOLD; ADSORPTION; MINERALS; KINETICS; METALS;
D O I
10.1016/j.mineng.2023.108534
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
Finding strategies that promote sustainability in the recovery of metals with industrial applications is imperative to reduce costs and mitigate environmental impacts. The use of environmentally friendly reagents such as glycine is being widely investigated due to the benefits that its application entails from an industrial, economic, and environmental perspective. We sought through this study to advance in the application of glycine leaching systems for the recovery of copper from different wastes and minerals while determining the optimal conditions for its recovery. Experimental results showed that among the 3 feedstocks tested (two mining wastes and one sulfide mineral) under the established operating conditions (room temperature and different alkaline pHs), the best copper recovery was obtained with the most oxidized waste at pH 9.5, which allowed a 100% of copper recovery along with low leaching of Fe and As. Furthermore, the characterization of its final post-leaching residue showed phytostimulant properties. Unfortunately, these selected conditions did not yield favorable re-sults for the sulfide mineral and the less oxidized wastes. In this case, further research will be necessary to achieve higher metal recoveries.
引用
收藏
页数:15
相关论文
共 50 条
  • [1] The selective leaching of copper from a gold-copper concentrate in glycine solutions
    Oraby, E. A.
    Eksteen, J. J.
    HYDROMETALLURGY, 2014, 150 : 14 - 19
  • [2] Selective complexation leaching of copper from copper smelting slag with the alkaline glycine solution: An effective recovery method of copper from secondary resource
    Huang, Yukun
    Wang, Dasong
    Liu, Hongtu
    Fan, Guixia
    Peng, Weijun
    Cao, Yijun
    SEPARATION AND PURIFICATION TECHNOLOGY, 2023, 326
  • [3] Selective Copper Recovery with HCl Leaching from Copper Oxalate Material
    Z. Abidin Sarı
    M. Deniz Turan
    Hasan Nizamoğlu
    Aslıhan Demiraslan
    Tolga Depci
    Mining, Metallurgy & Exploration, 2020, 37 : 887 - 897
  • [4] Selective Copper Recovery with HCl Leaching from Copper Oxalate Material
    Sari, Z. Abidin
    Turan, M. Deniz
    Nizamoglu, Hasan
    Demiraslan, Aslihan
    Depci, Tolga
    MINING METALLURGY & EXPLORATION, 2020, 37 (03) : 887 - 897
  • [5] Selective Separation Recovery of Copper and Arsenic from the Leaching Solution of Copper Soot
    Yang, Zhizhao
    Zhang, Yongbing
    Zhou, Hepeng
    Luo, Xianping
    Tang, Xuekun
    Liu, Zishuai
    METALS, 2022, 12 (11)
  • [6] A potential strategy for eco-friendly and efficient copper recovery: Ferricyanide-enhanced glycine leaching of copper
    Ma, Yonghe
    Li, Qian
    Zhang, Yan
    Liu, Xiaoliang
    Yang, Yongbin
    Jiang, Tao
    SEPARATION AND PURIFICATION TECHNOLOGY, 2025, 358
  • [7] Selective leaching process for the recovery of copper and zinc oxide from copper-containing dust
    Wu, Jun-Yi
    Chang, Fang-Chih
    Wang, H. Paul
    Tsai, Ming-Jer
    Ko, Chun-Han
    Chen, Chih-Cheng
    ENVIRONMENTAL TECHNOLOGY, 2015, 36 (23) : 2952 - 2958
  • [8] A study of copper recovery from copper-contaminated sludge with ferrite and selective leaching processes
    Hu, S. H.
    Wu, J. Y.
    Hsiao, T. C.
    Yen, F. S.
    Tsai, M. S.
    ENVIRONMENTAL PROGRESS, 2007, 26 (01): : 104 - 112
  • [9] Selective Recovery of Copper from Industrial Sludge by Integrated Sulfuric Leaching and Electrodeposition
    Trinh, Ha Bich
    Lee, Jaeryeong
    Kim, Seunghyun
    Lee, Jae-chun
    Aceituno, Juan Carlos Fuentes
    Oh, Seokhoon
    METALS, 2021, 11 (01) : 1 - 13
  • [10] Recovery of copper from heavy metal sludge with ferrite and selective leaching processes
    Hu, SH
    Hsiao, HY
    Wu, JY
    Yen, FS
    Tsai, MS
    PROCEEDINGS OF THE 8TH INTERNATIONAL SYMPOSIUM ON EAST ASIAN RESOURCES RECYCLING TECHNOLOGY-2005: RESOURCES RECYCLING TECHNOLOGY-2005, 2005, : 189 - 194