Synthesis and structures of homoleptic germylenes and stannylenes with sulfonimidamide ligands

被引：3

作者：

Lentz, Nicolas ^{[1
]}

Sodreau, Alexandre ^{[1
]}

Acuna, Alejandra ^{[1
,2
]}

Mallet-Ladeira, Sonia ^{[3
]}

Maerten, Eddy ^{[1
]}

Sotiropoulos, Jean-Marc ^{[4
]}

Rojas Guerrero, Rene Segundo ^{[2
]}

Madec, David ^{[1
]}

机构：

[1] Univ Toulouse, UPS, LHFA Lab Heterochim Fondamentale & Appl, UMR CNRS 5069, 118 Route Narbonne, F-31062 Toulouse 09, France

[2] Pontificia Univ Catolica Chile, Fac Quim & Farm, Dept Quim Inorgan, Vicuna Mackenna 4860,Macul, Santiago 7820436, Chile

[3] Inst Chim Toulouse ICT, UAR 2599, 118 Route Narbonne, F-31062 Toulouse 09, France

[4] Univ Pau & Pays Adour, CNRS, IPREM UMR 5254, Helioparc 2 Ave President Angot, F-64053 Pau, France

来源：

DALTON TRANSACTIONS | 2023年 / 52卷 / 20期

关键词：

STABILIZED GERMYLENES; COMPLEXES; BIS(SILYLENE); REACTIVITY; GERMANIUM; CRYSTAL; AMIDES;

D O I：

10.1039/d3dt01072d

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

An unusual series of germylenes and stannylenes with homoleptic symmetric and unsymmetric N-substituted sulfonimidamide ligands PhSO(NiPr)(NHiPr) 1 and PhSO(NMes)(NHiPr) 2 have been prepared by protonolysis reaction of Lappert's metallylenes [M(HMDS)(2)] (M = Ge or Sn) with two equivalents of the appropriate sulfonimidamide. The homoleptic germylenes [PhSO(NiPr)(2)](2)Ge 3 and [PhSO(NMes)(NiPr)](2)Ge 4, and stannylenes [PhSO(NiPr)(2)](2)Sn 5 and [PhSO(NMes)(NiPr)](2)Sn 6 were fully characterized by NMR spectroscopy and by X-ray diffraction analysis. DFT calculations have been performed to understand the electronic properties brought by the sulfonimidamide ligand.

引用

页码：6841 / 6846

页数：6

共 50 条

[1] Structures of germylenes and stannylenes with chelating ligands: a DFT study
Mengmeng, H.
Karlov, S. S.
Zabalov, M. V.
Zaitsev, K. V.
Lemenovskii, D. A.
Zaitseva, G. S.
RUSSIAN CHEMICAL BULLETIN, 2009, 58 (08) : 1576 - 1580
[2] Structures of germylenes and stannylenes with chelating ligands: a DFT study
H. Mengmeng
S. S. Karlov
M. V. Zabalov
K. V. Zaitsev
D. A. Lemenovskii
G. S. Zaitseva
Russian Chemical Bulletin, 2009, 58 : 1576 - 1580
[3] Germylenes and Stannylenes with Chelating Anilido-Imine Ligands: Syntheses, Structures and Reactivity
Mcheik, Ali
Katir, Nadia
Castel, Annie
Gornitzka, Heinz
Massou, Stephane
Riviere, Pierre
Hamieh, Tayssir
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2008, (34) : 5397 - 5403
[4] GERMYLENES AND STANNYLENES
NEUMANN, WP
CHEMICAL REVIEWS, 1991, 91 (03) : 311 - 334
[5] Syntheses and crystal structures of heteroleptic stannylenes and germylenes
Benet, S
Cardin, CJ
Cardin, DJ
Constantine, SP
Heath, P
Rashid, H
Teixeira, S
Thorpe, JH
Todd, AK
ORGANOMETALLICS, 1999, 18 (03) : 389 - 398
[6] CYCLOPENTADIENYL-SUBSTITUTED GERMYLENES AND STANNYLENES AS COMPLEX LIGANDS
JUTZI, P
HAMPEL, B
STROPPEL, K
KRUGER, C
ANGERMUND, K
HOFMANN, P
CHEMISCHE BERICHTE-RECUEIL, 1985, 118 (07): : 2789 - 2797
[7] New stable germylenes, stannylenes, and related compounds 7.* Synthesis and structures of compounds
Khrustalev, V. N.
Zemlyansky, N. N.
Borisova, I. V.
Kuznetsova, M. G.
Krut'ko, E. B.
Antipin, M. Yu.
RUSSIAN CHEMICAL BULLETIN, 2007, 56 (02) : 267 - 270
[8] Germylenes and stannylenes based on aminobisphenolate ligands: insertion into the C—Br bond
K. V. Zaitsev
E. A. Kuchuk
A. V. Churakov
G. S. Zaitseva
M. P. Egorov
S. S. Karlov
Russian Chemical Bulletin, 2017, 66 : 622 - 627
[9] Germylenes and stannylenes: Congeners of carbenes
Roesky, Herbert W.
Jana, Anukul
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2009, 237
[10] Novel germylenes and stannylenes based on pyridine-containing dialcohol ligands
Huang, Mengmeng
Lermontova, El'mira Kh.
Zaitsev, Kirill V.
Churakov, Andrei V.
Oprunenko, Yuri F.
Howard, Judith A. K.
Karlov, Sergey S.
Zaitseva, Galina S.
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2009, 694 (23) : 3828 - 3832

← 1 2 3 4 5 →