Studying the effectiveness of various chromophores of the 5-aryl-2,2′-bipyridine series for the sensitization of lanthanide(III) cations

被引：0

作者：

Majee, Adinath ^{[1
]}

Krinochkin, Alexey P. ^{[2
,3
]}

Valieva, Maria I. ^{[2
,3
]}

Starnovskaya, Ekaterina S. ^{[2
,3
]}

Shtaitz, Yaroslav K. ^{[2
]}

Kopchuk, Dmitry S. ^{[2
,3
]}

Santra, Sougata ^{[2
]}

Liu, Yuanli ^{[4
]}

Zyryanov, Grigory V. ^{[2
,3
]}

Chupakhin, Oleg N. ^{[2
,3
]}

机构：

[1] Visva Bharati Cent Univ, Dept Chem, Santini Ketan 731235, India

[2] Ural Fed Univ, Ekaterinburg 620002, Russia

[3] Russian Acad Sci, I Ya Postovsky Inst Organ Synth, Ural Branch, Ekaterinburg 620108, Russia

[4] Guilin Univ Technol, Coll Mat Sci & Engn, Guangxi Key Lab Opt & Elect Mat & Devices, Guilin 541004, Peoples R China

来源：

JOURNAL OF THE IRANIAN CHEMICAL SOCIETY | 2024年 / 21卷 / 03期

关键词：

Lanthanide complexes; Lanthanide cation luminescence; DTTA; 5-Aryl-2,2 '-bipyridine; 1,2,4-Triazine" methodology; DIELS-ALDER REACTION; COMPLEXES; LUMINESCENCE; 1,2,4-TRIAZINE; EUROPIUM; EU(III); LIGANDS; METHYL; EU3+;

D O I：

10.1007/s13738-023-02954-z

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A systematic study of the effectiveness of various chromophores of the 5-aryl-2,2'-bipyridine series was carried out in terms of sensitization of lanthanide(III) cations. For this purpose, the corresponding DTTA-appended 5-aryl-2,2'-bipyridines were synthesized in good yields by using the "1,2,4-triazine" methodology, and their europium(III) and terbium(III) complexes were prepared. The photophysical properties were studied for all the obtained chelates, and the influence of the nature of the aryl substituent of the bipyridine core was estimated. The positive influence of the halogen atoms as well as a methyl group on the efficiency of the lanthanide(III) cation sensibilization was demonstrated. The influence of the nature of the residue of the polyaminocarboxylic acid fragment in the ligand on the luminescent characteristics of its lanthanide complexes was also studied. [GRAPHICS] .

引用

页码：731 / 740

页数：10

共 13 条

[1] Studying the effectiveness of various chromophores of the 5-aryl-2,2ʹ-bipyridine series for the sensitization of lanthanide(III) cations
Adinath Majee
Alexey P. Krinochkin
Maria I. Valieva
Ekaterina S. Starnovskaya
Yaroslav K. Shtaitz
Dmitry S. Kopchuk
Sougata Santra
Yuanli Liu
Grigory V. Zyryanov
Oleg N. Chupakhin
Journal of the Iranian Chemical Society, 2024, 21 : 731 - 740
[2] Preparation of Ligands for Lanthanide Cations Based on 5-Aryl-2,2′-bipyridine-6′-carboxylic acids with an Extended Conjugation System
Krinochkin, Alexey P.
Kopchuk, Dmitry S.
Santra, Sougata
Zyryanov, Grigory, V
Rusinov, Vladimir L.
Chupakhin, Oleg N.
PROCEEDINGS OF THE II INTERNATIONAL CONFERENCE: MODERN SYNTHETIC METHODOLOGIES FOR CREATING DRUGS AND FUNCTIONAL MATERIALS (MOSM2018), 2019, 2063
[3] Luminescent neutral lanthanide complexes of 5-aryl-2,2′-bipyridine-6-carboxylic acids, synthesis and properties
Krinochkin, Alexey P.
Kopchuk, Dmitry S.
Kozhevnikov, Dmitry N.
POLYHEDRON, 2015, 102 : 556 - 561
[4] Novel neutral lanthanide complexes of 5-aryl-2,2′-bipyridine-6′-carboxylic acids with improved photophysical properties
Kopchuk, Dmitry S.
Krinochkin, Alexey P.
Kozhevnikov, Dmitry N.
Slepukhin, Pavel A.
POLYHEDRON, 2016, 118 : 30 - 36
[5] Convenient Synthetic Approach towards High Alcohol Esters of 5-Aryl-2,2′-bipyridine-5′-carboxylic Acids
Kopchuk, Dmitry S.
Starnovskaya, Ekaterina S.
Shtaitz, Yaroslav K.
Savchuk, Maria, I
Krinochkin, Alexey P.
Zyryanov, Grigory, V
Rusinov, Vladimir L.
Chupakhin, Oleg N.
MODERN SYNTHETIC METHODOLOGIES FOR CREATING DRUGS AND FUNCTIONAL MATERIALS (MOSM2019), 2020, 2280
[6] Water-soluble luminescent lanthanide complexes based on C6-DTTA-appended 5-aryl-2,2′-bipyridines
Krinochkin, Alexey P.
Kopchuk, Dmitry S.
Kim, Grigory A.
Shevyrin, Vadim A.
Santra, Sougata
Rahman, Matiur
Taniya, Olga S.
Zyryanov, Grigory, V
Rusinov, Vladimir L.
Chupakhin, Oleg N.
POLYHEDRON, 2020, 181 (181)
[7] Deciphering Three Beneficial Effects of 2,2′-Bipyridine-N,N′-Dioxide on the Luminescence Sensitization of Lanthanide(III) Hexafluoroacetylacetonate Ternary Complexes
Eliseeva, Svetlana V.
Pleshkov, Dmitry N.
Lyssenko, Konstantin A.
Lepnev, Leonid S.
Bunzli, Jean-Claude G.
Kuzmina, Natalia P.
INORGANIC CHEMISTRY, 2011, 50 (11) : 5137 - 5144
[8] A series of novel lanthanide complexes with 2-bromine-5-methoxybenzoic acid and 2,2′-bipyridine: Syntheses, crystal structures, and luminescent properties
Zhao, Qing-Qing
Zhu, Min-Min
Ren, Ning
Zhang, Jian-Jun
JOURNAL OF MOLECULAR STRUCTURE, 2017, 1149 : 171 - 182
[9] Dual Luminescent Tetranuclear Organogold(I) Macrocycles of 5,5′-Diethynyl-2,2′-bipyridine and Their Efficient Sensitization of Yb(III) Luminescence
Li, Xiu-Ling
Tan, Ming
Zhang, Ke-Juan
Yang, Bo
Chen, Jie
Ai, Yu-Bo
INORGANIC CHEMISTRY, 2012, 51 (01) : 109 - 118
[10] A series of lanthanide complexes with 2-fluorobenzoic acid and 5,5′-dimethyl-2,2′-bipyridine: Synthesis, supramolecular structures, spectroscopy and thermal behaviour
Du, Dan-Dan
Ren, Ning
Zhang, Jian-Jun
JOURNAL OF SOLID STATE CHEMISTRY, 2021, 300

← 1 2 →