Strong chiral optical force for small chiral molecules based on electric-dipole interactions, inspired by the asymmetrical hydrozoan Velella velella

被引:2
|
作者
Cameron, Robert P. [1 ,2 ]
McArthur, Duncan [1 ,2 ]
Yao, Alison M. [1 ,2 ]
机构
[1] Univ Strathclyde, SUPA, Glasgow G4 0NG, Scotland
[2] Univ Strathclyde, Dept Phys, Glasgow G4 0NG, Scotland
来源
NEW JOURNAL OF PHYSICS | 2023年 / 25卷 / 08期
关键词
chirality; chiroptics; optical forces; isotopic chirality; chiral resolution; matter-wave interferometry; CIRCULAR-DICHROISM SPECTROSCOPY; ROTATION; TOP;
D O I
10.1088/1367-2630/ace7ee
中图分类号
O4 [物理学];
学科分类号
0702 ;
摘要
Drawing inspiration from a remarkable chiral force found in nature, we show that a static electric field combined with an optical lin perpendicular to lin polarization standing wave can exert a chiral optical force on a small chiral molecule that is several orders of magnitude stronger than other chiral optical forces proposed to date, being based on leading electric-dipole interactions rather than relying on weak magnetic-dipole and electric-quadrupole interactions. Our chiral optical force applies to most small chiral molecules, including isotopically chiral molecules, and does not require a specific energy-level structure. Potential applications range from chiral molecular matter-wave interferometry for precision metrology and tests of fundamental physics to the resolution of enantiomers for use in chemistry and biology.
引用
收藏
页数:17
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