Spectroscopic and reactive characterization of mixed-metal Fe-Cr trimer nodes in metal-organic framework MIL-100

被引：4
|
作者：
Hall, Jacklyn N. [1 ]
Bollini, Praveen [1 ]
机构：
[1] Univ Houston, William A Brookshire Dept Chem & Biomol Engn, Houston, TX 77204 USA
来源：
CHEMICAL COMMUNICATIONS | 2023年 / 59卷 / 32期
关键词：
VIBRATIONAL-SPECTRA; SUBSTITUTION; COMPLEXES; OXIDATION; SITES;
D O I：
10.1039/d3cc00100h
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Metal-organic framework MIL-100 is synthesized featuring heterometallic Fe and Cr M3O nodes where mixing of the metals within the nodes is evidenced using a combination of in situ IR spectroscopy, NO titrations, and CO oxidation kinetics. Reactivity data indicate distinctive properties of the bimetallic nodes.
引用
收藏
页码：4758 / 4761
页数：4
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