Distribution, sources, and ecological risk assessment of polycyclic aromatic hydrocarbons in surface water in the coal mining area of northern Shaanxi, China

This study investigated the spatial distribution, pollution source, and ecological risk of polycyclic aromatic hydrocarbons (PAHs) in the Kuye River, which is a typical river in the mining area of China, 16 priority PAHs were quantitatively detected at 59 sampling sites by high-performance liquid chromatography-diode array detector-fluorescence detector. The results showed that the n-ary sumation PAHs concentrations in the Kuye River were in the range of 50.06-278.16 ng/L. The PAHs monomer concentrations were in the range 0-121.22 ng/L, of which chrysene had the highest average concentration (36.58 ng/L), followed by benzo[a]anthracene and phenanthrene. In addition, the 4-ring PAHs showed the highest relative abundance in the 59 samples, ranging from 38.59 to 70.85%. Moreover, the highest concentrations of PAHs were mainly observed in coal mining, industrial, and densely populated areas. On the other hand, according to the diagnostic ratios and positive matrix factorization (PMF) analysis, it can be concluded that coking/petroleum sources, coal combustion, vehicle emission, and fuel-wood combustion contributed to the PAHs concentrations in the Kuye River by 37.91%, 36.31%, 13.93%, and 11.85%, respectively. In addition, the results of the ecological risk assessment indicated that benzo[a]anthracene had a high ecological risk. Among the 59 sampling sites, only 12 belong to low ecological risk areas, and others were at medium to high ecological risks. The current study provides data support and a theoretical basis to effectively manage pollution sources and ecological environment treatment in mining areas.