Magnetocaloric properties and Griffiths phase of ferrimagnetic cobaltite CaBaCo4O7

We present a study on the magnetocaloric properties of a CaBaCo4O7 polycrystalline cobaltite along with research on the nature of magnetic phase transition. The magnetization as a function of temperature identifies the ferrimagnetic to paramagnetic transition at a Curie temperature of 60 K. Moreover, a Griffiths-like phase is confirmed in a temperature range above T (C). The compound undergoes a crossover from the first to second-order ferrimagnetic transformation, as evidenced by the Arrott plots, scaling of the universal entropy curve, and field-dependent magnetic entropy change. The maximum of entropy change is 3 J/kg.K for Delta H = 7 T at T (C), and a broadening of the entropy peak with increasing magnetic field indicates a field-induced transition above T (C). The analysis of the magnetic entropy change using the Landau theory reveals the second-order phase transition and indicates that the magnetocaloric properties of CaBaCo4O7 are dominated by the magnetoelastic coupling and electron interaction. The corresponding values of refrigerant capacity and relative cooling power are estimated to be 33 J/kg and 42 J/kg, respectively.