Structural Effect of Water-Soluble Zinc Porphyrins in a Visible-Light Driven NADH Regeneration System Catalyzed by Rhodium Pentamethylcyclopentadienyl Complex

被引：3
|
作者：
Takeuch, Mika [1 ]
Amao, Yutaka [1 ,2 ]
机构：
[1] Osaka Metropolitan Univ, Grad Sch Sci, 3-3-138 Sugimoto,Sumiyoshi Ku, Osaka 5588585, Japan
[2] Osaka Metropolitan Univ, Res Ctr Artificial Photosynth ReCAP, 3-3-138 Sugimoto, Sumiyoshi ku, Osaka 5588585, Japan
来源：
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN | 2023年 / 96卷 / 11期
关键词：
NADH regeneration; Zinc porphyrin; Photoredox system; HYDROGEN; PHOTOSYNTHESIS; EVOLUTION;
D O I：
10.1246/bcsj.20230137
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The effect of ionic substituents (4-sulfonatophenyl, 4-carboxy-phenyl, 4-methylpyridyl, and 4-N,N,N-trimethylaminophenyl-groups) of water-soluble zinc porphyrin (ZnP) on the visible light -driven NADH regeneration by a system of triethanolamine, ZnP, and rhodium complex [Cp*Rh(bpy)(H2O)]2+ (Cp* = pentamethylcyclo-pentadienyl, bpy = 2,2'-bipyridyl) was studied to provide significant guidance for hybridization with a wide range of oxidoreductases.
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页码：1206 / 1208
页数：3
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