Visible-light-induced cyclization of 2-alkenyl-1,1' - biphenyls

被引：5

作者：

Yan, Kang ^{[1
]}

Yang, Xingyu ^{[1
]}

Gao, Jiangang ^{[1
]}

Zhang, Ze ^{[1
]}

Li, Pinhua ^{[1
]}

机构：

[1] Anhui Polytech Univ, Coll Chem & Environm Engn, Wuhu 241000, Anhui, Peoples R China

来源：

ORGANIC CHEMISTRY FRONTIERS | 2023年 / 10卷 / 10期

基金：

中国国家自然科学基金;

关键词：

H BOND FUNCTIONALIZATION;

D O I：

10.1039/d2qo02052a

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A novel and efficient method for the preparation of phenanthrene-9,9(10H)-dicarbonitrile derivatives has been developed, which occurs through the cyclization of 2-malononitrilemethylene-substituted 1,1'-biphenyls under metal-free conditions. The transformation involves photoelectrocyclization via visiblelight mediated energy transfer catalysis and [1,5]-H shift, and the protocol has a range of advantages, including simplicity and mildness of the reaction conditions, environmental friendliness, good functional-group tolerance, and excellent yields of products.

引用

页码：2453 / 2458

页数：6

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