CRYSTAL STRUCTURE OF （Et4N）2[Mo6O（μ-O）12O5]

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作者：
Lu Shaofang Buang Jianquan Huang Zixiang Huang JinlingFuzhou Laboratory of Structural Chemistry
机构：
来源：
结构化学 | 1989年 / 01期
关键词：
一彻; Mo6O; CRYSTAL STRUCTURE OF; Et4N; O5;
D O I：
10.14102/j.cnki.0254-5861.1989.01.007
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学科分类号：
摘要：
Mr= 1140.4, tetragonal,P4/mnc,a=10.726(2), c=14.208(3)A, Z=2,Dc=2.316 g.cm-3,V=1634.5(9)A3,final R=0.050 for 1457 independent reflections. The anion [Mo6O19]2- has its No atoas in octahedral configuration with one oxygen atom situated in the center of the octahedron, twelve bridging oxygen atoms,and six terminal oxygen atoms. The average bond lengths of the three types of Mo-O bonds are 1.678 A (Mo=0), 1.919A [Mo-(μ-O)], and 2.310 A [Mo-(μs-O)], respectively.
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页码：27 / 30
页数：4
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