SYTHESIS AND ANIONIC POLYMERIZATION OF 2-METHYL-2-METHOXYCARBONYL-5-METHYLENE-1, 3-DIOXOLAN-4-ONE

被引：0

作者：

冯品珍

机构：

[1] Academia Sinica

[2] Beijing

[3] Department of Chemistry

[4] Graduate School

[5] P. O. Box 3908

来源：

Chinese Journal of Polymer Science | 1995年 / 01期

关键词：

Anionic polymerization; Ring opening polymerization; Cyclic monomer;

D O I：

暂无

中图分类号：

O631.5 [聚合反应、缩聚反应];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

A new cyclic monomer, 2-methyl-2-methoxycarbonyl-5-methylene-1,3-dioxolan-4-one,was synthesized successfully. The monomer and intermediate were characterized by;H NMR,;CNMR, INEPT（Intensive Nuclei Enhanced by Polarization Transfer） technique, IR and elementalanalysis. Anionic polymerization of the monomer was carried out in anhydrous THF at -70℃,and 9-fluorenyllithium was used as initiator. The polymer structure was determined by IR, NMRand elemental analysis. Molecular weight of the polymer was estimated by viscosity measurementin DMSO at 30℃.

引用

页码：35 / 40

页数：6

共 50 条

[1] SYNTHESIS AND ANIONIC POLYMERIZATION OF 2-METHYL-2-METHOXY CARBONYL-5-METHYLENE-1, 3-DIOXOLAN-4-ONE
冯品珍
Chinese Journal of Polymer Science, 1994, (04) : 372 - 378
[2] Synthesis and anionic polymerization of 2-methyl-2-methoxy carbonyl-5-methylene-1,3-dioxolan-4-one
Chin J Polym Sci (Engl Ed), 1 (35):
[3] Controlled radical polymerization and copolymerization of 5-methylene-2-phenyl-1,3-dioxolan-4-one by ATRP
Smith, Q
Huang, JY
Matyjaszewski, K
Loo, YL
MACROMOLECULES, 2005, 38 (13) : 5581 - 5586
[4] [3+2] Cycloaddition to a Chiral 5-Methylene-1,3-dioxolan-4-one and Pyrolysis of the Spiro Adducts
Aitken, R. Alan
Power, Lynn A.
Slawin, Alexandra M. Z.
MOLECULES, 2025, 30 (06):
[5] Synthesis and radical polymerization of 5-methylene-2,2-dimethyl-1,3-dioxolan-4-one
Miyagawa, T
Sanda, F
Endo, T
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2000, 38 (10) : 1861 - 1865
[6] BIPOLAR ADDITION OF DIAZOMETHANE TO 5-METHYLENE-1,3-DIOXOLAN-4-ONE
LIKHTEROV, VR
ETLIS, VS
KHIMIYA GETEROTSIKLICHESKIKH SOEDINENII, 1985, (09): : 1182 - 1184
[7] Radical copolymerization behavior of 2,2-dimethyl-5-methylene-1,3-dioxolan-4-one with common monomers
Miyagawa, T
Sanda, F
Endo, T
MACROMOLECULAR CHEMISTRY AND PHYSICS, 2001, 202 (09) : 1602 - 1605
[8] Synthesis of (R)-Lactic Acid and (2R, 5R)-2-tert-Butyl-5-methyl-1,3-dioxolan-4-one
Aitken, R. Alan
Meehan, Anna
Power, Lynn A.
SYNTHESIS-STUTTGART, 2015, 47 (11): : 1557 - 1559
[9] Synthesis of degradable poly(methyl methacrylate) via ATRP: Atom transfer radical ring-opening copolymerization of 5-methylene-2-phenyl-1,3-dioxolan-4-one and methyl methacrylate
Chung, IS
Matyjaszewski, K
MACROMOLECULES, 2003, 36 (09) : 2995 - 2998
[10] 2-(TERT-BUTYL)-CIS-5-(PARA-CHLOROPHENYLTHIO)-TRANS-5-METHYL-1,3-DIOXOLAN-4-ONE
BECKWITH, ALJ
CHAI, CLL
WILLIS, AC
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1992, 48 : 1362 - 1364

← 1 2 3 4 5 →