Synthesis and Luminescent Properties of Terbium Complexes with Acrylonitrile-co-styrene

被引：0
|
作者：
郭栋才 [1 ]
张真真 [1 ]
舒万艮 [2 ]
王鑫 [1 ]
机构：
[1] School of Chemistry and Chemical Engineering, Hunan University
[2] School of Chemistry and Chemical Engineering, Central South University
来源：
JournalofRareEarths | 2006年 / S2期
关键词：
acrylonitrile; styrene; complex; luminescence; rare earths;
D O I：
暂无
中图分类号：
O631..3 [];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Eight terbium complexes with aromatic carboxylic acid and acrylonitrile-co-styrene were fabricated by means of method from coordination to polymerization; and characterized by means of FT-IR and UV spectra analysis. Their thermal and luminescent properties were also investigated with thermal analysis and fluorescence spectra instruments, respectively. The results show that all terbium macro-molecule complexes possess nice thermal and luminescent properties. After terbium complexes ligands polymerized styrene, the change of molecule structures caused the energy transfer efficiency of ligands to change, and led to the luminescent intensity sequence of terbium complexes with aromatic carboxylic acid and acrylonitrile-co-styrene to be different from that of terbium complexes ligands.
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页码：1 / 6
页数：6
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