DIRECT MEASUREMENT OF MULTIPLE QUANTUM RELAXATION TIME

被引:0
|
作者
叶朝辉
许平
机构
[1] Cambridge University
[2] Laboratory of Magnetic Resonance and Atomic and Molecular Physics
[3] Academia Sinica
[4] PRC
[5] Wuhan 430071
[6] England
[7] PRC Department of Physical Chemistry
[8] Wuhan Institute of Physics
基金
中国国家自然科学基金;
关键词
MQ NMR; MQ relaxation; cross-correlation coefficient;
D O I
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中图分类号
学科分类号
摘要
A multiple quantum coherence (MQC) with a given order subjected to its own relaxa-tion decay in the evolution period can be transferred into observable single quantum (SQ)coherences in the detection period, the MQ relaxation time in a spin system, therefore, canbe directly measured by the 1-dimensional (1-D) Hahn echo method since the amplitudes ofSQC’s are modulated by the decayed MQC. This 1-D approach is an alternation to the 2-Dmeasurement for MQ relaxation time, the latter being somewhat time-consuming. The 1-Dapproaches can readily get rid of the inhomogeneous broadening of MQ lines. A method forselective measurement of various MQ relaxation times in AXsystems (n=1,2, and 3) witha given MQ order is presented. Consequently, the cross correlation coefficients of the sys-tems, which are not accessible in the SQ relaxation study, can be determined.
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页码:430 / 442
页数:13
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