Calculations of heat of solvation by a simple electrostatic approach to molecular interactions

被引：0
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作者：
CACHAU
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来源：
Chinese Journal of Chemistry | 1992年 / 02期
关键词：
Calculations of heat of solvation by a simple electrostatic approach to molecular interactions; heat;
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摘要：
An extremely simple formula to estimate the heat of formation of complexes between anion and a polar molecule or between highly polar systems is presented.The formula is entirelyelectrostatic and the expression used is verified by means of perturbation theory.This formula is test-ed for several ion-molecule and molecule-molecule pairs.It is also applied to estimate the heat ofhydration of simple salts.
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页码：107 / 116
页数：10
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