Unified treatment of one-range addition theorems for integer and non-integer n-STO, -GTO and -generalized exponential type orbitals with hyperbolic cosine in position, momentum and four-dimensional spaces

被引:0
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作者
I. I. Guseinov [1 ]
机构
[1] Department of Physics, Faculty of Arts and Sciences, Onsekiz Mart University
关键词
electronic structure; generalized exponential type orbitals; one-range addition theorems; Hartree-Fock-Roothaan equations;
D O I
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中图分类号
O561 [分子物理学];
学科分类号
摘要
Simpler formulas are derived for one-range addition theorems for the integer and noninteger n generalized exponential type orbitals, momentum space orbitals, and hyperspherical harmonics with hyperbolic cosine (GETO HC, GMSO HC, and GHSH HC) in position, momentum and four-dimensional spaces, respectively. The final results are expressed in terms of one-range addition theorems of complete orthonormal sets of ψα -exponential type orbitals, α - momentum space orbitals and z α -hyperspherical harmonics. We notice that the one-range addition theorems for integer and noninteger n-Slater type orbitals and Gaussian type orbitals in position, momentum and four dimensional spaces are special cases of GETO HC, GMSO HC, and GHSH HC. The theorems presented can be useful in the accurate study of the electronic structure of atomic and molecular systems.
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页码:176 / 178
页数:3
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